Abstract

The linear-dendritic polymer poly(ferrocenyldimethylsilane)-b-poly(benzyl ether) (PFS-PBE) films were prepared and their electrochemical behavior in LiClO 4 aqueous electrolyte solutions was investigated with cyclic voltammetry (CV). Reversible CV processes were obtained for PFS 27-PBE 1 film and irreversible CV processes were obtained for PFS 20-PBE 2 film in aqueous electrolyte solutions. The kinetic parameters such as the surface transfer coefficient, the apparent diffusion coefficient, and the standard rate constant for electron transfer, for the two films in aqueous LiClO 4 solutions were measured, and the electrode process mechanism of the films was also discussed.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call