Abstract
The charge transfer kinetics for the redox couple Ti(IV)/Ti(III) in the KCl-KF(10 wt.%)-K2TiF6 melt was studied. The standard rate constants of charge transfer (ks ) for the redox couple Ti(IV)/Ti(III) in the KCl-KF(10 wt.%)-K2TiF6 melt and the activation energy of charge transfer were calculated. Influence of strongly polarizing cations (Mg2+, Ca2+, Sr2+, and Ва2+) on the charge transfer kinetics was studied. It was determined the linear dependence of ks on the ionic potential of alkaline earth metal cations. The activation energies of charge transfer in case of strongly polarizing cations addition were found.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
