Abstract

The gamma-2 phase (Sn 8Hg) and a dental amalgam in phosphate buffer have been studied by means of potentiostatic and galvanostatic techniques, along with a rotating ring-disc electrode (RRDE). The analysis of results has shown that phosphate ions play an important role in the corrosion of amalgam. The anodic reaction leads to the formation of soluble species and a passivating film, which is probably composed of tin hydroxide and tin phosphate.

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