Electrochemical behavior and microstructural characterization of nano-SiC particles reinforced aluminum matrix composites prepared via friction stir processing

Abstract

The present work aims to elucidate the mechanism of microstructural evolution in different regions of nano-SiC particles reinforced aluminum matrix composites prepared by friction stir processing (FSP) on its electrochemical behavior. Electron backscatter diffraction technique (EBSD) and transmission electron microscopy (TEM) were employed to characterize the microstructure evolution of stir zone (SZ), advancing side thermomechanically affected zone (AS-TMAZ), retreating side thermomechanically affected zone (RS-TMAZ) and base metal (BM). The electrochemical behaviors of the above zones were investigated using electrochemical tests. A homogeneous and fine microstructure is formed in SZ, not only the nano-SiC is homogeneously distributed within the grains with an average grain size of 3.5 μm, but also the recrystallized grains account for the highest percentage of 85 %. The potentiodynamic polarization curve indicates that the corrosion current densities of the BM, RS-TMAZ, AS-TMAZ and SZ are 0.89, 0.39, 0.85 and 0.36 μA/cm2, respectively, while the polarization impedances are 33.40, 51.42, 48.72 and 73.79 kΩ cm2, respectively. Combining the Nyquist and Bode plots analysis, the optimal electrochemical corrosion resistance is in SZ. The fine and homogeneous recrystallized grains in SZ significantly improve its electrochemical corrosion resistance. This is mainly ascribed to the increase in crystal defects as a result of the increase in grain boundaries, elevating the electron scattering. Simultaneously, the increase in high-energy state grain boundaries is beneficial to the rapid formation of a thicker passivation film.