Abstract

In this paper, a novel needle-shaped Zinc organic framework was formed on the surface of a functionalized graphite electrode (Zn-MOF/CE) to create a methodical alternative electrode. The characterization of the Zn-MOF modifier was investigated via XRD, FT-IR, FESEM-EDS mapping, and N2 sorption. The redox behavior of the modified electrode was examined, showing high stability and conductivity under a diffusion-controlled process as a desirable working electrode. Also, the redox process of hydroquinone, as an organic molecule model, at the surface of the modified electrode was investigated and its operation was optimized and modeled by the central composite design (CCD) method. Based on the obtained results and CCD model, the process exhibited the best performance in scan rate 560 mV/s, pH= 9.9. Moreover, the frequency domain using bode plots, and two identical electrical models were evaluated by CCD results that could be employed in stability and electrode material performance prediction.

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