Abstract

The anodic behaviour of AISI 304 and 316 L s.s. in chloride ions containing solutions and in living sea water was studied. The effects of a number of parameters (metal composition, structure, cold working, heat treatments, surface finishing, electrode mounting) were investigated in order to obtain a statistical determination of the reliability of the electrochemical measurements concerning corrosion potentials, pitting and crevice breakdown potentials, sensitization towards intergranular corrosion. The scattering of the experimental results is discussed in terms of the reproductibility of both the measured electrochemical values and the phenomena themselves.

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