Abstract
Dehalogenation polycondensations of 2,6-dichloroquinoline with electrochemically generated zerovalent nickel complex and isolated zerovalent nickel complex afford π-conjugated poly(quinoline-2,6-diyl) (P(2,6-Q)) in high yields. Comparison of the polymerizations using various dihaloquinolines and dihaloisoquinolines as the monomer reveals that the electrochemical polymerization is more sensitive to the position of halogen in the monomer than the chemical polymerization and proceeds most smoothly for 2,6-dihaloquinoline
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