Abstract
The process of indirect cathodic amination of benzene is studied in aqueous media containing 4-10 M H2SO4 and, accordingly, 13.8–7.1 M CH3CN. At 50°C, electrolysis in the system of Ti(IV)–NH2OH–C6H6 results in formation of aniline and also small amounts of isomeric phenylenediamines and diphenyl. The current efficiency of aniline is maximum in the catholyte containing 8 M H2SO4 and 9.4 M CH3CN. Under these conditions, full conversion of hydroxylamine is observed; the 80% current efficiency of aniline corresponds to the efficiency of the amino radical source and its mass fraction among the products of electrolysis exceeds 97%.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
