Abstract
Replacing the oxygen evolution reaction in water electrolysis with ammonia oxidation reaction enables low voltage hydrogen production. Pt is a promising catalyst for the ammonia oxidation reaction due to its superior dehydrogenation and low affinity for *N, but Nads poisoning deactivates the Pt surface. This study proposes a method to improve ammonia oxidation performance and stability through electrochemical activation, introducing cathodic corrosion and recovery conditions. The half-cell results showed a peak current density of 74.2 mA cm−2 and retention ratio of 17 %. Adjusting the lower and upper cell voltage in a membrane electrode assembly based single cell optimized surface cleaning and inhibits further poisoning by O/OHads above 0.75 Vcell. Furthermore, incorporation of recovery conditions can enhance the stability of poisoned electrode compared to that in chronoamperometry test. The results of pulsed ammonia electrolysis tests incorporating recovery conditions suggested a novel approach to practical hydrogen production by stabilizing catalysts with a 83 % Faradaic efficiency at 0.1 A cm−2
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