Abstract
Long-chain hydrocarbons and oxygenates are used as fuels as well as in many daily applications. The majority of these molecules are derived from fossil fuels, which is a non-renewable commodity. The electrocatalytic CO2 reduction reaction (eCO2RR) has been recently found promising in producing C4+ molecules. Herein, we summarize recent works on this topic. The design of C4+ -producing catalysts is compared with those that produce C1-C3 products. Mechanisms for the C–C coupling step are reviewed.
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