Electrocatalytic nitrate reduction to ammonia on defective Au1Cu (111) single-atom alloys

Abstract

Electrocatalytic reduction of nitrate (NO3–) to ammonia (NH3) in wastewater is a promising economic process for NH3 synthesis. This work designed and prepared Au1Cu (111) single-atom alloys with surface Cu vacancies (VCu-Au1Cu SAAs), which exhibited superior NH3 Faradaic efficiency (98.7%) with a production rate of 555 μg h–1 cm–2 at −0.2 V vs. RHE, while negligible activity decay was found after a durability test. Meanwhile, 97% of produced NH3 can be recovered by a simple membrane distillation. Characterizations evidence that electron migration from Cu to Au atoms creates electron-deficient Cu active sites in VCu-Au1Cu SAAs, which promote the generation of active hydrogen species (*H) that can readily hydrogenate NO3–. Theoretical calculation reveals that the bi-functional Cu sites not only promote the activation of water to produce *H but also lower the energy barrier of *NH3 desorption from the catalyst surface.