Abstract

Ti-doped CeO2 mixed oxide powders (CeO2-TiO2) were synthesized by a sol-gel method with varying amount of Ti. The XRD patterns of CeO2-TiO2 (10 and 20 mol% Ti) powders calcined at 800°C for 4 h did not show the TiO2 phase. The electrical conductivity of CeO2-TiO2 mixed oxide was higher than that of CeO2 between 650 and 750°C under reducing atmosphere. The electrocatalytic activity of Ni/CeO2 and Ni/CeO2-TiO2 cermet anodes were examined under the oxidation of methane for solid oxide fuel cells (SOFCs). The Ni/CeO2-TiO2 (20 mol% Ti) anode showed a higher power density than that Ni/CeO2 in both H2 and CH4 fuels. The enhancement of methane oxidation was most likely to be caused by the higher electrical conductivity of the mixed ionic and electronic CeO2-TiO2 oxide cermet. The electrode polarization of the Ti-doped CeO2 anode was lower than that of the non-doped CeO2 anode.

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