Abstract

The influence of specific magnetic susceptibility on hydrogen overvoltage of Ni based co-deposits has been investigated for a better understanding of the role of magnetic susceptibility in hydrogen evolution. The hitherto reports on a correlation between bulk solid state properties and electrocatalytic activity have portrayed a negative picture. Our results on four systems namely NiMoFe, NiMoFeMn, NiZnFe and NiMn electrodeposits demonstrate that in each of the systems studied, electrocoating with highest magnetic susceptibility exhibits best electrocatalytic activity. This behaviour has been explained by hypothesising the existence of a new class of particles called “magnesons”.

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