Abstract
In this study, the catalytic effect of 2,2'-dipyridylamine (DPA) on the reduction of oxygen (O2) at the polarized water/1,2-dichloroethane (DCE) interface was investigated. Ferrocene (Fc) and tetrathiafulvalene (TTF) were weak electron donors used in this study. Slow reduction of O2 at the interface containing Fc and TTF was significantly accelerated upon the addition of DPA. Voltammetry and biphasic shake flask experiments revealed that DPA acts as a proton ionophore to transfer protons between the aqueous and organic phases. The PA, GB, and pKa values of all possible conjugate acids of DPA were calculated. Then, a mechanism was suggested to explain the interaction between protonated DPA and oxygen molecular. The mechanism was computationally analyzed by using density functional theory (DFT). Furthermore, DFT calculations at the B3LYP/6-31G** level of theory showed that the conjugate acid species of DPA transfer proton to O2 at the interface. The results show that DPA-H2+ and DPA-H1+ are the best species to transfer proton to molecular oxygen.
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