Electro-optic Kerr effect in the isotropic phase above the columnar phase of a urea derivative

Abstract

The authors have measured the electro-optic Kerr effect in the isotropic phase of a urea derivative. Electric-field-induced birefringence Deltan was observed in the isotropic phase even 30 degrees C above the isotropic-columnar phase transition temperature. The induced birefringence is inversely proportional to temperature, as predicted by the Landau-de Gennes theory. Two distinct regions are identified from the proportionality constants in the isotropic phase; optical second-harmonic generation (SHG) is easily observable in the low-temperature region on applying an electric field, whereas SHG activity does not emerge in the higher-temperature region. The structure of molecular assemblies is discussed based on these experimental results.