Abstract

AbstractThe cover picture shows two examples of electroinduced formation and transformation of oxido‐bridged manganese complexes with polypyridyl ligands. The first example displays interconversion between mononuclear, dinuclear and tetranuclear cores accompanied by the concomitant formation (by oxidation) or breaking (by reduction) of μ‐oxido bridges. In the second example, core interconversion between μ‐oxido and μ‐acetato bridges in dinuclear manganese complexes is depicted. The background picture shows a schematic representation of the photoinduced formation of a dinuclear di‐μ‐oxido‐bridged manganese core from a mononuclear one in a superstructured complex of ruthenium and manganese. Details are presented in the Microreview by M.‐N. Collomb and A. Deronzier on p. 2025 ff. The authors thank Dr. Damien Jouvenot for his help in designing the cover picture.

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