Abstract
Carbon quantum dots (CQDs) have been extensively explored in diverse fields because of their exceptional features. The nanometric particles with photoluminescence (PL) benefit various optical and photonic applications. However, the majority of previous reports have mainly focused on either unpolarized or circular-polarized (CP) PL. Linearly polarized (LP) emission of CQDs is limited mainly because of their isometric shape and difficulties in macroscopic orientation control. Herein, we report syntheses of anisometric CQDs and facile control of the uniaxial orientation on a macroscopic scale, which results in linearly polarized photoluminescence (LP-PL). The anisometric CQDs are synthesized from rigid-rod-shaped precursors and evenly dispersed in the rod-like liquid crystal (LC) host. As-synthesized CQDs exhibit a PL quantum yield as high as 35% in chloroform. In addition to uniform alignment, facile directional switching of the elongated CQD is established by employing the electrical responsiveness of the CQD and host LC. Therefore, the dichroic photophysical properties of anisometric CQDs have been beneficially adopted for fabrications of polarization-sensitive and electrically switchable PL devices. Also, anisometric CQDs are embedded in polymer films with molecular orientational patterns and clearly recognized by LP-PL.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.