Abstract

The preparation and physical properties of conducting ionomers were investigated. A two-step process was used to prepared polyethylene based film grafted with polystyrene sulphonic acid. Two methods, both based on chemical polymerization of pyrrole using ferric chloride, were conducted to form the conducting ionomers in aqueous solutions. In one method the polymerization agent was electrochemically recycled. The conductivity, structure, composition and mechanical properties of the conducting ionomers prepared in the two methods were evaluated and compared. Films having high conductivities and improved mechanical properties were obtained.

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