Abstract
The absolute thermoelectric power S has been measured for the system Cu–Pb from the liquidus to 1100°C. The whole phase diagram has been explored. The thermoelectric power of these alloys has, to our knowledge, never been measured before. These experimental results as well as those of the electrical resistivity (C. Chaı̈b, J.G. Gasser, Z. Phys. Chem. Neue Folge 156 (1988) S483–S487) are interpreted and discussed in terms of the extended Ziman formula using the t-matrix formalism with hard-sphere structure factors. The concentration and energy dependence of the phase shifts have been taken into account for a complete resistivity and thermopower calculation.
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