Abstract
Measurements of surface potential (Δ V) and surface tension (Δσ) of aqueous solutions of acetic acid, chloro-, dichloro-, trichloroacetic acid, and alcohols (methanol, ethanol, 2,2,2-trifluoroethanol) were used for the determination of effective dipole moments (μ̄) and their separate components. For this purpose, the Helmholtz equation (in the form presented by Demchak and Fort (5)) have been applied. The contributions from the reorientated water molecules ( μ ̄ 1/ϵ 1 ), and from hydrophilic ( μ ̄ φ- COOH , μ ̄ φ- OH ) and hydrophobic ( μ ̄ φ- CH 3 , μ ̄ φ- CH 2Cl , μ ̄ φ- CHCl 2 , μ ̄ φ- CF 3 ) groups and the local dielectric permittivity in the vicinity of these groups were calculated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
