Electrical measurements on the 2503 m Dome F Antarctic ice core

Abstract

AbstractThe 320 kyr climatic record from the 2503 m Dome Fuji (Antarctica) ice core was analyzed using two electrical methods: AC-ECM and ECM (electrical conductivity measurements). AC-ECM is a method to detect the complex admittance between electrodes dragged on the ice surface with mm-scale resolution and uses 1V and 1 MHz. the ratio of the real to imaginary part of the admittance is the AC loss factor, which responds linearly to the amount of sulfuric acid and hydrogen ions. Both the AC loss factor and the ECM current respond to acid, but the ECM signal tends to saturate at high acidities. Dome Fuji ice was measured to be highly acidic, with background values of 2–7 μM, and had 4500 major peaks with acidities of up to 90 μM. This ice-core evidence and earlier snow-chemistry survey around the dome region indicates that Dome F may have a better connection to the stratosphere than have sites at lower altitude, which allows more stratospheric aerosol and gases to reach the snow surface. Acidity tends to be high in interglacial periods, but correlation between acidity and δ18O is not straightforward. Electrical signals decreased and smoothed out with increasing depth; the diffusion coefficients deduced from this smoothing were 10–102 times greater than in solid ice. the ice core exhibited electromechanical effects and expelling effects from sulfate peaks.