Abstract

Polycrystalline bulk samples of double layered manganite system La 1.2(Sr 1− x Ca x ) 1.8Mn 2O 7 (0.0 ≤ x ≤ 0.4) were prepared by sol–gel method. After characterizing the samples using XRD and SEM, their electrical, magnetic and elastic properties were investigated. The lattice parameters and cell volume show a monotonous decrease with increase of Ca content, whereas the grain size is found to increase with increasing Ca content. The value of T IM is found to decrease with Ca content up to x = 0.3 and then a slight increase of T IM is observed. The low temperature upturn of resistivity is attributed to the spin-glass-like behavior, which is also evidenced by the irreversibility observed between ZFC and FC magnetizations. The conduction mechanism above T IM can be explained by Mott VRH model. The present magnetization and ultrasonic studies indicate that the system shows a secondary transition at T *, which decreases with increasing Ca content. Further, the T * seems to be intrinsic to the present double layered manganite system.

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