Abstract
The differential capacitance-potential dependence C(E) of electrolytically grown (111) and (100) faces of silver single crystals in diluted solutions of NaClO4 and KF was studied. Comparison with results obtained in KF solutions shows a concentration-independent shift of Emin to more negative potentials and higher values of the reciprocal slope of the C−1 vs. Cd−1 plots. The data obtained have been explained as due to a weak specific adsorption of ClO4− which is stronger on the (100) face. The influence of water in the double layer on the adsorption has been discussed.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Paper version not known
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
