Electrical and mechanical properties of partially bio‐based PP/PBS blends nanocomposites elaborated by twin‐screw extrusion

Abstract

AbstractOrganically modified montmorillonite (OMMT, Cloisite 20) was used as reinforcing filler to prepare nanocomposites from a blend of polypropylene (PP) and eco‐friendly degradable polybutylene succinate (PBS). A PP grafted with maleic anhydride was also added as a compatibilizer. Scanning electron microscopy observations indicated that the blend morphology was affected by the presence of OMMT, which acted as a compatibilizer between PP and PBS. Rheological measurements showed a significant increase of the complex viscosity when OMMT was added above a certain amount. X‐ray diffraction indicated an intercalated structure for all nanocomposites. The addition of OMMT improved mechanical properties of neat matrices and blends. The electrical insulation properties were preserved for low concentrations of OMMT, up to 2 wt%. Then, to guarantee good mechanical properties without deteriorating electrical ones, while maintaining a sufficient bio‐based composition, the 70/30 (PP/PBS) blend with clay concentrations of less than 2 wt% appeared to be the most satisfactory nanocomposite for applications in the field of electrical insulation.