Abstract
The intrinsic conductivities of thin films and single crystals of bis(phthalocyaninato)lutetium, Pc 2Lu, are reported for the first time. Pc 2Lu is shown to be more conductive than the usual metallophthalocyanines (PcM) by more than six orders of magnitude. Electron spin resonance (ESR) determinations on Pc 2Lu in solution, on sublimed powders or on a monocrystalline solvate demonstrate (i) the radical nature of the complex, (ii) the effect of dioxygen on the spin state, (iii) the extent of interaction between the molecular subunits.
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