Abstract

Anticlinic smectic-C surfaces were found experimentally as ground state structures in free-standing films made of smectic liquid crystals with no anticlinic bulk phases. A mean-field interpretation of this observation is given within a discrete phenomenological model of antiferroelectric liquid crystals, which additionally considers the enhanced order present at the surfaces of the free-standing films. The temperature dependence of the critical electric field that drives the transition between the anticlinic and synclinic smectic-C surfaces is evaluated, and fair agreement with the experimental data is found.

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