Abstract
Controlling material hysteresis and working frequency variability are fundamentally important for refrigeration cycle efficiency and power density in solid-state cooling systems. For elastocaloric cooling, understanding the relationship between the width of the stress hysteresis and elastocaloric behaviour during superelastic cycles under varied strain rates is important. In this work, we report the effects of strain rate effects on the superelastic and elastocaloric responses in Ni45Mn50−xInxCo5 (x = 13.6–14.0 in at%) polycrystalline alloys. We observed a strong correlation between stress hysteresis and superelastic stability during mechanical cycling under increasing strain rates. Excellent transformation reversibility and stable superelastic responses are observed for x = 13.6 with a narrow hysteresis (49 MPa), whereas transformation irreversibility and dramatically deteriorated superelastic stability occur for x = 13.8, with a wide hysteresis (138 MPa). Furthermore, isothermal loading–unloading cycles under increasing and constant maximum applied stress were performed for the x = 13.6 samples, with a combination of low transformation stress and small transformation hysteresis. We suggest that a balance between transformation strain and hysteresis energy loss is fundamental to achieving a high coefficient of performance for elastocaloric materials.
Highlights
Controlling material hysteresis and working frequency variability are fundamentally important for refrigeration cycle efficiency and power density in solid-state cooling systems
In terms of an elastocaloric cooling system, progress has been made in developing an elastocaloric prototype cooler[13], optimizing the cooling system design via numerical simulation[28], and achieving a system coefficient of performance (COP, as high as 7) superior to that for magnetocaloric Gd15, 29
Variations in the strain rate are desirable to achieve elastocaloric cooling with variable frequency, and high power density is expected with a high frequency
Summary
Controlling material hysteresis and working frequency variability are fundamentally important for refrigeration cycle efficiency and power density in solid-state cooling systems. The effect of stress hysteresis on superelasticity cycling stability under various strain rates has not been clarified. We observed a significant correlation between the stress hysteresis and superelastic stability under mechanical cycling with increasing strain rates.
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