Abstract
Herein, physicochemical features of poly(acrylic acid-co-acrylamide) hydrogels were studied via swelling, SEM, TGA, DTA and thermoporometric measurements as well Monte-Carlo simulations. Physicochemical characteristics of metal–embedded hydrogel nanocomposites were investigated by ICP-OES, XRD, SEM/EDX and HRTEM analysis. Catalytic behaviour of nanocomposites was examined through multi-repetitive oxidative degradation of methylene blue (MB) from wastewater. Decay of MB concentrations was followed up kinetically by UV–vis spectrophotometer and TOC analyzer. Poly(acrylic acid-co-acrylamide) hydrogels are promising candidates for embedding diverse-shaped nano-sized metallic species (Co, Cu, Ni and Fe) with advanced protectiveness behaviour against deactivation during degradation processes. Surface-sited nanometals developed pseudo-first ordered degradation profiles with inferior reusability trends. Bulk-sited nanometals exhibited strong tendency towards MB mineralization, obeying pseudo-second ordered progression. Hydrogel embedding nickel nanocomposite served as typical “Auto-active” catalyst regarding to its ability to gather reactants and radicals beneath nanometallic particles deep inside monolithics, thereby preserving the reduced metallic form throughout the degradation processes.
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