Abstract
The sampling process at the surface of steel samples under the conditions used in spectrometric analysis is essentially influenced by the thermal conductivity and the structure of the samples. It was established that the sampling rate and the penetration depth and the form of the sparked craters are directly related with the thermal conductivity of the samples and the temperature prevailing in the vicinity of the craters. A high thermal conductivity of the steel sample gives rise to wider and shallower craters and to smaller sampling rates than a low thermal conductivity.
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