Abstract
Abstract A spirometallocyclic complex of ruthenium with (CH3)2P(CH2)2, (CH3)2PCH2 and two (CH3)3P ligands (formula 5) is synthesized from (CH3)2P(CH2)2Li and trans-[(CH3)3P]4RuCl2 in the molar ratio 2:1. Two equivalents of (CH3)3P are liberated and the ionic complex trans-[(CH3)3P]4Ru[CH2P(CH3)3]Cl +Cl- is formed as a by-product. The products were characterized by analytical and spectroscopic data.
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