Abstract

The reaction of (2,6-tBu2-4-MeC6H2O)P(Cl)(CCPh) with Co2(CO)8 yields the neutral phosphenium ion complex (R)(R')P???Co(CO)3 (R = 2,6-tBu2-4-MeC6H2O; R' = (η2-CCPh)Co2(CO)6), a compound with a phosphorus cobalt double bond.

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