Abstract
EHT rotational energy curves are presented for various nicotinamides and benzamide. The conformations calculated for nicotinamide and benzamide are comparable to those determined by X-ray methods. Protonation, N-methyl substitution and the introduction of a ring nitrogen meta to the amide group are discussed in terms of the corresponding calculated effect on the rotational energy curves. Some implications for the conformation of NAD⊕ are presented.
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