Efflorescence of fly ash-based geopolymer mortars under quasinatural conditions: the relationship between curing temperature, ion transport, and compressive strength

Abstract

This investigation reports the effect of curing temperatures ranging from 20 °C to 80 °C on the efflorescence of fly ash-based geopolymer mortars under quasinatural conditions. The microstructures of the geopolymers before and after efflorescence were characterized by SEM and MIP, respectively. These characterizations are adopted to further explain the change in compressive strength. The micromorphology and phase assemblage of the efflorescence products were identified by SEMEDS and XRD, respectively, indicating that the significant ions involved in the efflorescence include Ca2+, Na+, and CO32-; then, the concentrations of those ions in the leachate were detected by ICP, AAS, and acidbase neutralization titration, respectively. The results show that low curing temperatures (≤ 50 °C) promote the diffusion of ions into the leachate, while high curing temperatures (> 50 °C) contribute to the transportation of ions towards the drying part for the formation of hollow structured Na2CO3·7H2O. Although the increase in the compressive strength of the geopolymers resulting from efflorescence decreased with increasing curing temperature, the 50 °C-cured geopolymer exhibited the highest compressive strength during efflorescence. This study provides a reference for mitigating efflorescence and improving practicability in the hydraulic engineering of geopolymers.