Abstract

Concise synthesis of a 6-deoxy-α- l-talose tetrasaccharide, 6-deoxy-α- l-Tal p-(1→3)-6-deoxy-α- l-Tal p-(1→2)-6-deoxy-α- l-Tal p-(1→3)-6-deoxy-α- l-Tal p, the dimer of the disaccharide repeating unit of the OPS from Aggregatibacter actinomycetemcomitans serotype c, has been accomplished through suitable protecting group manipulations and stereoselective glycosylation starting from commercially available l-rhamnose. The target oligosaccharide in the form of its p-methoxyphenyl glycoside is suitable for further glycoconjugate formation via selective cleavage of this group.

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