Efficient Spin-Orbit Torque Generation in Semiconducting WTe2 with Hopping Transport

Abstract

Spin-orbit torques (SOTs) originated from the spin-orbit interactions in various types of materials systems and magnetic heterostructures have been shown to be an effective mechanism to manipulate and switch the magnetization in contemporary magnetic memory devices. When it comes to materials with sizable efficiency of generating spin current from charge current, 5d transition metals such as Pt [1], Ta [2], and W [3] are the representative candidates due to the sizable spin Hall effect (SHE). More recently, topological insulators (TIs) are reported to possess high SOT efficiency from spin momentum locking of the topologically-protected surface states (TSSs) [4]. Another family of emergent materials, transition metal dichalcogenides (TMDs), have also gained lots of attention due to not only the strong SOC but also their unconventional SOT features from the lack of inversion symmetry. Particularly, for exfoliated WTe2, it is proposed to exhibit anomalous spin torques and extremely large damping-like (DL) SOT efficiency [5, 6]. However, most of the previously studied crystalline WTe2 are prepared by mechanical exfoliation, which limits their potentials for industrial application. It is therefore crucial to explore the possibilities of employing WTe2 layers prepared by conventional materials growth approaches, such as magnetron sputter deposition, to see their spin transport properties as compared to the exfoliated cases.In this work, we report the DL-SOT efficiencies from both stoichiometric WTe2 and co-sputtered W100-xTex-based magnetic heterostructures prepared by high vacuum sputter depositions. Both series of deposited multilayer stacks are amorphous. We first quantify the damping constant of WTe2/CoFeB devices with in-plane magnetic anisotropy (IMA) through ST-FMR measurements, from which the damping constant is determined to be αWTe2/CoFeB=0.009±0.001, smaller than those obtained from control samples with classical spin Hall transition metals, namely Pt/CoFeB (αPt/CoFeB=0.033±0.003) and W/CoFeB (αW/CoFeB=0.014±0.002). The largest DL-SOT efficiency from the stoichiometric WTe2/CoTb devices with perpendicular magnetic anisotropy (PMA) is further estimated to be ξDLWTe2∼0.20 by current-induced hysteresis loop shift measurement, which are greater than those of the W-based control sample (ξDLW∼-0.04). To give further evidence of the sizable DL-SOT efficiency in WTe2, we perform the current-induced magnetization switching measurement from WTe2/CoTb devices. As shown in Fig. 1, the switching polarities depend on the applied Hx, which is consistent with the SOT-driven switching mechanism. More importantly, the critical switching current density Jc of WTe2/CoTb structure is further demonstrated to be Jc∼7.05×109 (A/m2), which is much lower than those from the 5d transition metal-based heterostructures (Jc∼1011 A/m2). Note that this value is of the same order as the exfoliated 80 nm-thick-WTe2 case reported by Shi. S et al. (Jc∼3×109 A/m2) [6]. All of the advantages mentioned above indicate that the amorphous sputtered WTe2 is a competitive SOT source in the emergent chalcogenide materials category.To explore the possible origins of SOT in the amorphous WTe2 heterostructures, we turn to compare the stoichiometric WTe2 with co-sputtered W82Te18 samples. Fig. 2 shows the SOC layer thickness dependence of │ξDL│ from both type of samples. For the co-sputtered case, the thickness dependence of efficiency can be well fitted by the spin diffusion model, which suggests that the SOC within W82Te18 is of bulk origin (such as the SHE). In contrast, for WTe2, │ξDLWTe2│ decays with increasing the stoichiometric layer thickness, which indicates the possible existence of interfacial contributions of SOC besides the bulk effect. We speculate that interfacial effects could play crucial roles on the SOT generation in the Te-rich (stoichiometric) regime, even if the TMD layer is amorphous. Further studies are required to elucidate the SOC and SOT generation mechanisms in these amorphous TMD systems.Lastly, we turn our focus on the electrical transport properties of amorphous WTe2. Most of the previous works claimed that the textured WTe2 is one kind of Weyl semimetal, while our sample is predominately amorphous and therefore should not fall into this category. To get insight into the electron transport behavior behind, we investigate the temperature dependence of resistivity from the amorphous WTe2. The amorphous WTe2 is inclined to behave as semiconductor rather than metal or semimetal. Within the absence of periodic lattices and band structure, the hopping mechanism such as the small polaron hopping (SPH) model is more suitable to describe the phenomenon [7]. In high temperature regime (323-423K), the resistivity of WTe2 can be well fitted by the SPH model, which indicates that thermally-activated hopping polarons from electron-lattice interaction dominate the transport mechanism behind, and therefore suggests that the sputtered amorphous WTe2 is semiconducting with hopping transport property. **