Efficient sky-blue cesium lead bromide light-emitting diodes with enhanced stability via synergistic interfacial induction and polymer scaffold inhibition

Abstract

All inorganic CsPbX3 perovskite has aroused broad interests in building efficient light-emitting devices with wide color gamut and flexible fabrication process. So far, the realization of high-performance blue perovskite light-emitting devices (PeLEDs) is still a critical challenge. Herein, we propose an interfacial induction strategy to generate low-dimensional CsPbBr3 with sky blue emission by employing γ-aminobutyric acid (GABA) modified poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). The interaction between GABA and Pb2+ inhibited the formation of bulk CsPbBr3 phase. Further assisted by the polymer networks, the sky-blue CsPbBr3 film exhibited much improved stability under both photoluminescence and electrical excitation. This can be ascribed to the scaffold effect and the passivation function of the polymer. Consequently, the obtained sky-blue PeLEDs exhibited an average external quantum efficiency (EQE) of 5.67% (maximum of 7.21%) with a maximum brightness of 3308 cd/m2 and a working lifespan reaching 0.41 h. The strategy in this work provides a new opportunity for exploitation the full potential of blue PeLEDs towards application in lighting and display devices.