Efficient Removal of Tannic Acid from Olive Mill Wastewater Using Carbon Steel Slag

Abstract

Mediterranean countries experience a large production of olive oil, thus generating huge quantities of non-biodegradable vegetation waters. The discharge of these effluents into aquatic environments seriously affects the quality of surface waters. This study investigated the potential use of carbon steel slag (SS) as an adsorbent and improver for reducing olive mill wastewater (OMWW) toxicity. The elemental and structural characterization of SS was carried out using inductively coupled plasma-optical emission spectrometry (ICP/EOS), X-ray fluorescence (XRF), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and Brunauer–Emmett–Teller (BET) analysis. OMWW characterization indicated that the effluent was acidic in nature, with a pH of 4.8, a higher conductivity reaching 14.92 mS/cm, higher COD of 157.31 g/L, rich in organic matter 112.33 g/L, and total phenolic compounds of 11.13 g/L. The neutralization capacity of SS was demonstrated by reducing the OMWW’s acidic character. Afterward, the adsorption of tannic acid (TA) was investigated using SS. Parameters such as contact time, initial TA concentration, adsorbent dosage, pH, and temperature were investigated. The kinetic study indicated that the adsorption of TA onto SS fitted well with the second pseudo-order (r = 0.99) and Elovich (r = 0.98) models, indicating that the adsorption of TA was mainly chemical and depends on the reactions of oxide hydrolysis and hydroxides dissolution. Moreover, Langmuir isotherm has greatly described the adsorption of TA on SS (R = 0.997), suggesting that the surface of SS is homogenous, and the adsorption occurs mainly in monolayer. The maximum adsorption capacity reached 714.28 mg/g, indicating the higher capacity of SS to reduce the polyphenolic compounds in OMWW. This study demonstrated that SS residue from the steelmaking industry could present a highly interesting material for OMWW remediation.