Efficient removal of methylene blue from aqueous solution by ZIF-8-decorated helicoidal electrospun polymer strips

Abstract

Immobilization of metal-organic frameworks (MOFs) on electrospun products for wastewater treatment has garnered considerable attention in recent years. However, the effect of the overall geometry and surface-area-to-volume ratio of MOF-decorated electrospun architectures on their performances have rarely been investigated. Herein, we prepared polycaprolactone (PCL)/polyvinylpyrrolidone (PVP) strips with helicoidal geometries via immersion electrospinning. By regulating the weight ratio of PCL to PVP, the morphologies and surface-area-to-volume ratios of the PCL/PVP strips could be controlled precisely. Then, the zeolitic imidazolate framework-8 (ZIF-8) for removing methylene blue (MB) from an aqueous solution was immobilized on the electrospun strips, resulting in ZIF-8-decorated PCL/PVP strips. The key characteristics of these composite products, such as adsorption and photocatalytic degradation behavior toward MB in the aqueous solution, were carefully investigated. Owing to the desired overall geometry and high surface-area-to-volume ratio of the ZIF-8-decorated helicoidal strips, a high MB adsorption capacity of 151.6 mg g−1 was obtained, which is significantly higher than those with conventional electrospun straight fibers. In addition, higher MB uptake rates, higher recycling and kinetic adsorption efficiencies, higher MB photocatalytic degradation efficiencies, and faster MB photocatalytic degradation rates were confirmed. This work provides new insights to improve the performance of existing and potential electrospun product-based water treatment strategies.