Abstract

In this study, a magnetic copper ferrite/montmorillonite-k10 nanocomposite (CuFe2O4/MMT-k10) was successfully fabricated by a simple sol-gel combustion method and was characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), the Brunner–Emmett–Teller (BET) method, vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS). For levofloxacin (LVF) degradation, CuFe2O4/MMT-k10 was utilized to activate persulfate (PS). Due to the relative high adsorption capacity of CuFe2O4/MMT-k10, the adsorption feature was considered an enhancement of LVF degradation. In addition, the response surface methodology (RSM) model was established with the parameters of pH, temperature, PS dosage, and CuFe2O4/MMT-k10 dosage as the independent variables to obtain the optimal response for LVF degradation. In cycle experiments, we identified the good stability and reusability of CuFe2O4/MMT-k10. We proposed a potential mechanism of CuFe2O4/MMT-k10 activating PS through free radical quenching tests and XPS analysis. These results reveal that CuFe2O4/MMT-k10 nanocomposite could activate the persulfate, which is an efficient technique for LVF degradation in water.

Highlights

  • In recent years, pharmaceuticals and personal care products (PPCPs), as emerging contaminants, have been detected frequently in the environment, which has caused widespread concern

  • 2O4/montmorillonite k10 (MMT-k10) composite was was investigated investigated by byXRD

  • Results property of CuFe2 O4 and CuFe2 O4 /MMT-k10 was measured by vibrating sample magnetometer (VSM)

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Summary

Introduction

Pharmaceuticals and personal care products (PPCPs), as emerging contaminants, have been detected frequently in the environment, which has caused widespread concern. Antibiotics, as one kind of PPCPs, are widely used in the treatment of pathogenic-organism diseases of humans or livestock [1,2]. The long-term discharge of low-dose antibiotics into the environment will lead to the prompted drug resistance of sensitive bacteria. Water 2020, 12, 3583 genes might develop and interfere with environment, posing a potential threat to the ecological environmental security and human health [5]. The traditional water treatment process may not meet the demands of effective removal of antibiotic contamination. It is important to develop an efficient and eco-friendly technique to remove antibiotics in waste water

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