Abstract
A novel adsorbent, the uniform fiber ball (UFB) loaded with polypyrrole (UFB-PPy), was synthesized for Cr(VI) removal from water in this paper. The structure of the UFB and UFB-PPy were characterized by SEM, EDS, FT-IR, BET, XPS and TG. The adsorption properties of UFB-PPy towards Cr(VI) were investigated by the effects of temperature, initial concentration of Cr(VI), interfering ions and contact time in batch experiments, the isothermal models (Langmuir, Freundlich and Temkin) and the kinetic models (Pseudo first-order kinetic, Pseudo second-order kinetic and Intra-particle diffusion models) were used to describe the adsorption behavior. The effects of the initial concentration and flow rate of the Cr(VI) solution in the column experiments were also studied, and the dynamic models (Yoon-Nelson, Adams-Bohart and Wolborska model) were applied to predict the adsorption performance. The Cr(VI) removal mechanism of UFB-PPy was revealed by studying the effect of pH on adsorption, testing of Cl−, and analyzing the XPS. The results showed that UFB-PPy exhibited excellent adsorption properties for Cr(VI) both in batch and column adsorption. The possible adsorption mechanism involved electrostatic attraction, ion exchange and reduction. Conveniently, the chromium resources can be recovered with the form of high-purity Cr2O3 by simple calcination of Cr(VI)-captured UFB-PPy (UFB-PPy-Cr).
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
