Efficient removal of both heavy metal ion and dyes from wastewater using magnetic response adsorbent of block polymer brush-grafted N-doped biochar

Abstract

The recovery of biomass from agricultural and forestry waste could realize effective utilization of waste and synthesis of novel adsorbent. Herein, porous biochar was prepared from waste ginkgo biloba leaves and modified by Reversible Addition-Fragmentation Chain Transfer Polymerization (RAFT). And the prepared adsorbent exhibited excellent adsorption capacity owing to its abundant functional groups and porous structure. In addition, the adsorption capacities of the prepared adsorbent for Malachite Green (MG), Amaranth (AM) and Cr (Ⅵ) were 422.59, 373.75 and 368.82 mg/g, respectively, surpassing those of many previously reported materials. Subsequently, the influence of various factors on adsorption performance was studied. The results showed that adsorption of MG, AM and Cr (Ⅵ) on adsorbent followed pseudo-second-order and Langmuir models and the adsorbent also displayed excellent cycling performance. The experimental results of application in various water samples showed that the adsorbent had outstanding adsorption performance in real water samples, further proving that the adsorbent had wide application and practicability. Finally, a simple adsorption column was used for filtration experiments to simulate industrial application. The results were exhibited that the adsorbent had great potential in treating wastewater containing MG, AM and Cr (Ⅵ).