Efficient photocatalytic hydrogen production using an NH4TiOF3/TiO2/g-C3N4 composite with a 3D camellia-like Z-scheme heterojunction structure

Abstract

Photocatalysis is one of the most promising ways to realize artificial photosynthesis. The biologically inspired photocatalysts with 3D flower-like structures have attracted much attention. In this study, an effective method for the synthesis of composite photocatalytic material, NH4TiOF3/TiO2/g-C3N4, with a 3D camellia-like structure, was developed. The 3D hierarchical structure of the composite material enabled multiple refractions and reflections of light within the catalyst, which greatly improved the efficiency of the sunlight harvesting. The combination of NH4TiOF3 and TiO2 also effectively reduced the electron-hole recombination in the g-C3N4. To evaluate its photocatalytic performance, the prepared nanostructured composite materials were tested for the water-splitting with simulated sunlight. It showed the hydrogen evolution at the rate of 3.6 mmol/g/h, which is 4.0 times faster than that from the pure g-C3N4. The composite materials exhibited excellent cycling stability. The detailed mechanism of the Z-scheme heterojunction was also discussed. The proposed synthesis route for the creation of 3D flower-like hierarchical composites provides a new effective technique for developing efficient, active, and stable composite photocatalysts for hydrogen production.