Efficient oxidative degradation of 2-chlorophenol and 4-chlorophenol over supported CuO-based catalysts

Abstract

A series of metal oxide catalysts for catalytic oxidative degradation of 2-chlorophenol (2-CP) and 4-chlorophenol (4-CP) were prepared, and the supported CuO catalysts were studied particularly. The supported CuO catalysts were characterized by XRD and NH 3-TPD techniques, in which CUO/γ-AI 2O 3 exhibited high degradation activity. The addition of Na 20 or K 2O into CUO/γ-AI 2O 3 improved the oxidative degradation of CPs remarkably, in which Na 20 was more efficient than K 2O. Over CuO/γ-Al 2O 3-Na 20, CPs were completely converted and the liberation of the inorganic chloride from 2-CP or 4-CP reached 97% or 100% respectively at 30 °C for 2 h. The supported CuO catalysts with good dispersion of CuO particles and less acid sites were favorable for the efficient oxidative degradation of CPs. In addition, the initial pH of the reaction solution was found to be an important factor which influenced the catalytic oxidative degradation of CPs and the initial pH of 11.2 and 9.8 was preferred for the oxidative degradation of 2-CP and 4-CP respectively over CUO/γ-AI 2O 3 catalyst.