Abstract
C 60 molecule exhibited high reactivity towards the addition reaction of nitrogen dioxide radicals (·NO 2), which were generated by reaction of sodium nitrite with conc. HNO 3. This chemical functionalization of C 60 resulted in polynitro fullerenes, C 60(NO 2) n. Hydrolysis of polynitro fullerenes in aqueous NaOH gave the corresponding polyhydroxylated fullerene derivatives (fullerenols) in moderate overall yields. Results from mass spectra (FAB, negative ion) of fullerenols indicated their structure as C 60 derivatives with at least 16 hydroxy groups.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.