Abstract
Using iron bipyridine or phenanthroline complexes 1 as redox catalysts it was possible to electrochemically generate NAD(P) + from NAD(P)H very efficiently. Electrochemically driven enzymatic oxidations of the test systems 2-hexen-1-ol and 2-butanol could be performed with 1e as redox catalyst in presence of yeast alcohol dehydrogenase (YADH) or the alcohol dehydrogenase of thermoanaerobium brockii (TADH) with turnover numbers of about 40/h.
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