Abstract

Abstract In the present work, efficient epoxidation of alkenes with sodium periodate catalyzed by tetraphenylporphyrinatomanganese(III) chloride, Mn(TPP)Cl, and octabromotetraphenylporphyrinatomanganese(III) chloride, Mn(Br 8 TPP)Cl, using (1- n -butyl-3-methylimidazolium tetrafluoroborate), [bmim][BF 4 ], as ionic liquid is reported. The effect of substituted bromines on the catalytic activity and reusability of manganese porphyrins was also investigated.

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