Efficient Electron Transfer by Plasmonic Silver in SrTiO3 for Low-Concentration Photocatalytic NO Oxidation.

Abstract

Photocatalysis presents a feasible option to control low-concentration NO emissions from industrial burning facilities, and increasing excitons in quantity and improving surface activity are the crucial issues to be solved. Plasmonic silver with the orientation of the (111) plane is uniformly distributed on the Ti-O termination of the SrTiO3 (STO) (100) plane (major). The NO conversion rate has a sixfold increment compared to pristine STO. Meanwhile, the toxic NO2 had a significant decline in the absence of water. This high performance could be attributed to the unique property of the localized surface plasmonic resonance of silver particles, which increases the optical response range of the catalyst. Meanwhile, the formation of a Schottky junction could promote the charge separation and enhance the lifetime of excitons via the electron transfer from silver particles to STO. More importantly, the Ag-O bond of the heterojunction increases the charge density of adjacent Ti, preferring to bond with the antibonding orbital electron of adsorbed molecules, which offers a favorable channel for the NO adsorption and activation of reactive oxidation species.