Abstract
Electrochemical synthesis, from manganese strips and dissolved linker, of a new amine-containing manganese-based metal–organic framework with enhanced CO2 uptake.
Highlights
Coordination chemistry has evolved as a most promising route to porous materials with precisely decorated interiors to obtain specific properties for versatile applications.[1]
Metal–organic frameworks have metal coordination sites bridged by organic ligands in highly ordered networks that often afford well defined structures, high crystallinity and large surface areas that can be used in catalysis, or gas separation applications.[4,5]
Further details are given in Table S2† and the structures for Mn–BDC and Mn–DABDC(ES) are shown in Fig. 1 & 2 respectively
Summary
Coordination chemistry has evolved as a most promising route to porous materials with precisely decorated interiors to obtain specific properties for versatile applications.[1]. Samples of the Mn–DABDC framework were prepared using the conventional solvothermal method to compare synthetic outcomes with the product obtained by electrochemical synthesis.
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