Efficient Cr(VI) sequestration from aqueous solution by chemically modified Garcinia kola hull particles: characterization, isotherm, kinetic, and thermodynamic studies.

Abstract

There is a need for the removal of hexavalent chromium from contaminated water prior to its discharge into the environment, as part of industrial effluents, due to its toxic nature. In this present study, an adsorbent prepared via chemical modification of Garcinia kola hull particles (GK-HP) using NaOH was applied for Cr(VI) sequestration from aqueous solution. Both the raw (rGK-HP) and chemically modified Garcinia kola hull particles (cMGK-HP) were characterized using BET, SEM, XRD, FTIR, TGA, and EDS. The effects of pH, contact time, adsorbent dose, adsorbate initial concentration, and temperature on Cr(VI) sequestration were examined. The adsorbent, cMGK-HP, proved to be more effective for the adsorption process than rGK-HP with 96.25% removal efficiency at a pH of 2, a contact time of 60 min, an adsorbent dose of 5 g/L, Cr(VI) initial concentration of 20 mg/L and a temperature of 40°C. Isotherm and kinetic studies showed experimental data to be well-fitted with Langmuir isotherm and follow the pseudo-second-order kinetic model. The thermodynamic study revealed adsorption nature to be feasible, occur via physisorption, spontaneous, and exothermic. Changes in morphological structure, textural property, spectral peak, phase composition, and chemical composition of adsorbents before and after Cr(VI) sequestration from solution were proved by SEM, BET, FTIR, XRD, and EDS analyses, respectively. cMGK-HP possessed excellent reusability attribute and high thermal stability as shown by TGA. In conclusion, the adsorption capacity of cMGK-HP is better than many other adsorbents generated from agrowastes used in previous studies for Cr(VI) removal.