Efficient coal-based power generation via optimized supercritical water gasification with chemical recuperation

Abstract

Supercritical water gasification (SCWG) is promising as a clean coal technology and is an emerging topic of interest in sustainable energy. Here, we introduce a clean and efficient power generation system that optimizes SCWG of coal through chemical recuperation. Central to our approach is the innovative utilization of both exhaust and a portion of the syngas as dual heat sources for gasification, simultaneously producing the requisite supercritical water. This chemical recuperation strategy effectively enhances the transformation of coal chemical energy into syngas. The introduced system achieves power generation and exergy efficiencies of 56.64 and 55.30%, respectively, outperforming those of a baseline system by 8.43 and 8.23%, respectively. This gain is primarily attributed to the irreversible losses in the gasification, air separation, and heat-exchange processes of the introduced system, which were reduced by 8.75, 2.47, and 4.17%, respectively, compared with the corresponding values of the baseline system. In order to elucidate and validate the reduced irreversible losses in the introduced system compared with those in the baseline system, we incorporated the energy utilization diagram methodology into our analysis. In summary, the introduced system represents a pivotal advancement in clean and efficient coal-based power generation and underscores the need for continuous innovation in this sector.